Bis[3-dimethylamino-1-(pyridin-2-yl)prop-2-en-1-one-κ2N1,O]tris(nitrato-κ2O,O)gadolinium(III) ethanol disolvate

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Bis[3-dimethyl­amino-1-(pyridin-2-yl)prop-2-en-1-one-κ2 N 1,O]tris­(nitrato-κ2 O,O)gadolinium(III) ethanol disolvate

In the title compound, [Gd(NO(3))(3)(C(10)H(12)N(2)O)(2)]·2C(2)H(5)OH, the Gd(III) ion and one nitrate anion are located on a twofold rotation axis. The Gd(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(N,N-dimethyl-amino)-1-(2-pyrid-yl)prop-2-en-1-one) ligands and six O atoms from three nitrate anions in a distorted bicapped square-anti-prismatic geometry. In the cr...

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(E)-1-{4-[Bis(4-meth­oxy­phen­yl)meth­yl]piperazin-1-yl}-3-(3,4-dieth­oxy­phen­yl)prop-2-en-1-one ethanol disolvate

The asymmetric unit of the title compound, C(32)H(38)N(2)O(5)·2C(2)H(6)O, contains one main mol-ecule and two solvent mol-ecules, which inter-act via inter-molecular O-H⋯O hydrogen bonds. The piperazine ring adopts a chair conformation. The crystal packing exhibits weak inter-molecular C-H⋯O hydrogen bonds and voids of 31 Å(3).

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(E)-1-(Pyridin-2-yl)-3-(3,4,5-trimeth­oxy­phen­yl)prop-2-en-1-one

In the title heteroaryl chalcone derivative, C(17)H(17)NO(4), the dihedral angle between the pyridine and benzene rings is 10.82 (5)°. The two meth-oxy groups at the meta positions are essentially coplanar with the attached benzene rings [C-O-C-C torsion angles = -0.97 (14) and 179.47 (9)°], whereas the meth-oxy group at the para position is twisted from the attached ring with a C-O-C-C torsion...

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(2E)-1-(Pyridin-2-yl)-3-(2,4,6-trimeth­oxy­phen­yl)prop-2-en-1-one

The title heteroaryl chalcone derivative, C(17)H(17)NO(4), is a condensation product of 2-acetyl-pyridine and 2,4,6-trimeth-oxy-benzaldehyde. The mol-ecule is roughly planar, the dihedral angle between the pyridine and benzene rings being 5.51 (10)°. All the three meth-oxy groups are almost co-planar with the bound benzene ring [r.m.s. deviation of 0.0306 (2) Å]. A weak C-H⋯O intra-molecular in...

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(2E)-3-(3-Bromo-4-meth­oxy­phen­yl)-1-(pyridin-2-yl)prop-2-en-1-one

The mean planes of the benzene and pyridine rings in the title compound, C(15)H(12)BrNO(2), are nearly coplanar, subtending an angle of 2.8 (8)°. The prop-2-en-1-one group is also in the plane of these rings with an N-C-C-O torsion angle of 179.6 (3)°. A weak C-H⋯Br inter-molecular inter-action contributes to the crystal packing, creating a chain-like structure along the a axis.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811050458